%O Copyright © P. K. Humire et al. 2022. Open Access article, published by EDP Sciences, under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. %T Methanol masers in NGC 253 with ALCHEMI %I EDP SCIENCES S A %J Astronomy & Astrophysics %A PK Humire %A C Henkel %A A Hernández-Gómez %A S Martin %A J Mangum %A N Harada %A S Muller %A K Sakamoto %A K Tanaka %A Y Yoshimura %A K Nakanishi %A S Mühle %A R Herrero-Illana %A DS Meier %A E Caux %A R Aladro %A R Mauersberger %A S Viti %A L Colzi %A VM Rivilla %A M Gorski %A KM Menten %A K-Y Huang %A S Aalto %A PP van der Werf %A KL Emig %X Context. Methanol masers of Class I (collisionally pumped) and Class II (radiatively pumped) have been studied in great detail in our Galaxy in a variety of astrophysical environments such as shocks and star-forming regions and are they are helpful to analyze the properties of the dense interstellar medium. However, the study of methanol masers in external galaxies is still in its infancy. / Aims. Our main goal is to search for methanol masers in the central molecular zone (CMZ; inner 500 pc) of the nearby starburst galaxy NGC 253. / Methods. Covering a frequency range between 84 and 373 GHz (λ = 3.6–0.8 mm) at high angular (1.″6 ∼ 27 pc) and spectral (∼8–9 km s−1) resolution with ALCHEMI (ALMA Comprehensive High-resolution Extragalactic Molecular Inventory), we have probed different regions across the CMZ of NGC 253. In order to look for methanol maser candidates, we employed the rotation diagram method and a set of radiative transfer models. / Results. We detect for the first time masers above 84 GHz in NGC 253, covering an ample portion of the J−1 → (J − 1)0 − E line series (at 84, 132, 229, and 278 GHz) and the J0 → (J − 1)1 − A series (at 95, 146, and 198 GHz). This confirms the presence of the Class I maser line at 84 GHz, which was already reported, but now being detected in more than one location. For the J−1 → (J− 1)0 − E line series, we observe a lack of Class I maser candidates in the central star-forming disk. / Conclusions. The physical conditions for maser excitation in the J−1 → (J − 1)0 − E line series can be weak shocks and cloud-cloud collisions as suggested by shock tracers (SiO and HNCO) in bi-symmetric shock regions located in the outskirts of the CMZ. On the other hand, the presence of photodissociation regions due to a high star-formation rate would be needed to explain the lack of Class I masers in the very central regions. %L discovery10152832 %V 663 %D 2022 %K galaxies: spiral; galaxies: starburst; masers; submillimeter: galaxies; radio lines: galaxies