Motherwell, WB;
Moreno, RB;
Pavlakos, I;
Arendorf, JRT;
Arif, T;
Tizzard, GJ;
Coles, SJ;
(2018)
Noncovalent Interactions of π Systems with Sulfur - The Atomic Chameleon of Molecular Recognition.
Angewandte Chemie
, 130
(5)
pp. 1207-1212.
10.1002/ange.201708485.
Preview |
Text
Aliev_Motherwell_Manuscript_16Nov17_Unmarked.pdf - Accepted Version Download (697kB) | Preview |
Abstract
The relative strength of noncovalent interactions between a thioether sulfur atom and various π systems in designed top pan molecular balances was determined by NMR measurements. Compared to its oxygen counterpart, the sulfur atom displays a remarkable ability to interact with almost equal facility over the entire range of π systems studied, with the simple alkene emerging as the most powerful partner. With the exception of the O···heteroarene interaction, all noncovalent interactions of sulfur with π systems are favoured over oxygen.
| Type: | Article |
|---|---|
| Title: | Noncovalent Interactions of π Systems with Sulfur - The Atomic Chameleon of Molecular Recognition |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/ange.201708485 |
| Publisher version: | http://dx.doi.org/10.1002/ange.201708485 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10038625 |
Archive Staff Only
 |
View Item |
