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Aluminium/gallium, indium/gallium, and aluminium/indium co-doped ZnO thin films deposited via aerosol assisted CVD

Potter, DB; Powell, MJ; Parkin, IP; Carmalt, CJ; (2018) Aluminium/gallium, indium/gallium, and aluminium/indium co-doped ZnO thin films deposited via aerosol assisted CVD. Journal of Materials Chemistry C , 6 (3) pp. 588-597. 10.1039/c7tc04003b. Green open access

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Abstract

Aluminium/gallium co-doped ZnO (AGZO), indium/gallium co-doped ZnO (IGZO), and aluminium/indium co-doped ZnO (AIZO) thin films were synthesised on glass substrates via aerosol assisted chemical vapour deposition (AACVD). The films were fully characterised by X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. The optoelectronic properties of the films were determined using UV/vis spectroscopy and Hall effect measurements. The AGZO film displayed the lowest resistivity (1.3 × 10−2 Ω cm) and highest carrier mobility (7.9 cm2 V−1 s−1), due the relatively low amount of disorder in the structure. The incorporation of In3+ resulted in the most disorder in the structure due to its large radius, which led to an increase in optical absorption, and a decrease in resistivity.

Type: Article
Title: Aluminium/gallium, indium/gallium, and aluminium/indium co-doped ZnO thin films deposited via aerosol assisted CVD
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/c7tc04003b
Publisher version: http://dx.doi.org/10.1039/c7tc04003b
Language: English
Additional information: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/)
Keywords: CHEMICAL-VAPOR-DEPOSITION, ZINC-OXIDE FILMS, TRANSPARENT CONDUCTING OXIDES, DONOR FUNCTIONALIZED ALCOHOLS, PULSED-LASER DEPOSITION, MOLECULAR-BEAM EPITAXY, ELECTRICAL-PROPERTIES, SPRAY-PYROLYSIS, SUBSTRATE-TEMPERATURE, PHYSICAL-PROPERTIES
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10043458
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