Rosillo-Lopez, M;
Salzmann, CG;
(2018)
Highly efficient heavy-metal extraction from water with carboxylated graphene nanoflakes.
RSC Advances
, 8
(20)
pp. 11043-11050.
10.1039/c8ra00823j.
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Abstract
Heavy metals such a lead or cadmium have a wide range of detrimental and devastating effects on human health. It is therefore of paramount importance to efficiently remove heavy metals from industrial wastewater streams as well as drinking water. Carbon materials, including graphene and graphene oxide (GO), have recently been advocated as efficient sorption materials for heavy metals. We show that highly carboxylated graphene nanoflakes (cx-GNF) outperform nano-graphene oxide (nGO) as well as traditional GO with respect to extracting Fe 2+ , Cu 2+ , Fe 3+ , Cd 2+ and Pb 2+ cations from water. The sorption capacity for Pb 2+ , for example, is more than six times greater for the cx-GNF compared to GO which is attributed to the efficient formation of lead carboxylates as well as strong cation-π interactions. The large numbers of carboxylic acid groups as well as the intact graphenic regions of the cx-GNF are therefore responsible for the strong binding of the heavy metal cations. Remarkably, the performance of the as-made cx-GNF can easily compete with previously reported carbon materials that have undergone additional chemical-functionalisation procedures for the purpose of heavy-metal extraction. Furthermore, the recyclability of the cx-GNF material with respect to Pb 2+ loading is demonstrated as well as the outstanding performance for Pb 2+ extraction in the presence of excess Ca 2+ or Mg 2+ cations which are often present under environmental conditions. Out of all the graphene materials, the cx-GNF therefore show the greatest potential for future application in heavy-metal extraction processes.
| Type: | Article |
|---|---|
| Title: | Highly efficient heavy-metal extraction from water with carboxylated graphene nanoflakes |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/c8ra00823j |
| Publisher version: | http://doi.org/10.1039/c8ra00823j |
| Language: | English |
| Additional information: | © The Royal Society of Chemistry 2018. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10046939 |
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