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Increasing carbon fiber composite strength with a nanostructured "brick-and-mortar" interphase

De Luca, F; Clancy, AJ; Carrero, NR; Anthony, DB; De Luca, HG; Shaffer, MSP; Bismarck, A; (2018) Increasing carbon fiber composite strength with a nanostructured "brick-and-mortar" interphase. Materials Horizons , 5 (4) pp. 668-674. 10.1039/c7mh00917h. Green open access

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Abstract

Conventional fiber-reinforced composites suffer from the formation of critical clusters of correlated fiber breaks, leading to sudden composite failure under tension. To mitigate this problem, an optimized "brick-and-mortar" nanostructured interphase was developed, in order to absorb energy at fiber breaks and alleviate local stress concentrations whilst maintaining effective load transfer. The coating was designed to exploit crack bifurcation and platelet interlocking mechanisms known in natural nacre. However, the architecture was scaled down by an order of magnitude to allow a highly ordered conformal coating to be deposited around conventional structural carbon fibers, whilst retaining the characteristic phase proportions and aspect ratios of the natural system. Drawing on this bioinspiration, a Layer-by-Layer assembly method was used to coat multiple fibers simultaneously, providing an efficient and potentially scalable route for production. Single fiber pull-out and fragmentation tests showed improved interfacial characteristics for energy absorption and plasticity. Impregnated fiber tow model composites demonstrated increases in absolute tensile strength (+15%) and strain-to-failure (+30%), as compared to composites containing conventionally sized fibers.

Type: Article
Title: Increasing carbon fiber composite strength with a nanostructured "brick-and-mortar" interphase
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/c7mh00917h
Publisher version: https://doi.org/10.1039/c7mh00917h
Language: English
Additional information: This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10053192
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