Balan, E;
Noireaux, J;
Mavromatis, V;
Saldi, GD;
Montouillout, V;
Blanchard, M;
Pietrucci, F;
... Gaillardet, J; + view all
(2018)
Theoretical isotopic fractionation between structural boron in carbonates and aqueous boric acid and borate ion.
Geochimica et Cosmochimica Acta
, 222
pp. 117-129.
10.1016/j.gca.2017.10.017.
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Abstract
The11B/10B ratio in calcite and aragonite is an important proxy of oceanic water pH. However, the physico-chemical mechanisms underpinning this approach are still poorly known. In the present study, we theoretically determine the equilibrium isotopic fractionation properties of structural boron species in calcium carbonates, BO33−, BO2(OH)2−and B(OH)4−anions substituted for carbonate groups, as well as those of B(OH)4−and B(OH)3species in vacuum. Significant variability of equilibrium isotopic fractionation properties is observed among these structural species which is related to their contrasted coordination state, B–O bond lengths and atomic-scale environment. The isotopic composition of structural boron does not only depend on its coordination number but also on its medium range environment, i.e. farther than its first coordination shell. The isotopic fractionation between aqueous species and their counterparts in vacuum are assessed using previous investigations based on similar quantum-mechanical modeling approaches. At 300 K, the equilibrium isotope composition of structural trigonal species is 7–15‰ lighter than that of aqueous boric acid molecules, whereas substituted tetrahedral borate ions are heavier than their aqueous counterparts by 10–13‰. Although significant uncertainties are known to affect the theoretical prediction of fractionation factors between solids and solutions, the usually assumed lack of isotopic fractionation during borate incorporation in carbonates is challenged by these theoretical results. The present theoretical equilibrium fractionation factors between structural boron and aqueous species differ from those inferred from experiments which may indicate that isotopic equilibrium, unlike chemical equilibrium, was not reached in most experiments. Further research into the isotopic fractionation processes at the interface between calcium carbonates and aqueous solution as well as long duration experiments aimed at investigating the kinetics of equilibration of boron environment and isotopic composition are therefore required to refine our understanding of boron coprecipitation in carbonates and thus the theory behind the use of boron isotopes as an ocean pH proxy.
| Type: | Article |
|---|---|
| Title: | Theoretical isotopic fractionation between structural boron in carbonates and aqueous boric acid and borate ion |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1016/j.gca.2017.10.017 |
| Publisher version: | https://doi.org/10.1016/j.gca.2017.10.017 |
| Language: | English |
| Additional information: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
| Keywords: | Boron pH-proxy, Ab initio modeling, Theoretical isotopic fractionation factors, Calcium carbonates |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10053688 |
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