Chubb, KL; Naumenko, O; Keely, S; Bartolotto, S; Macdonald, S; Mukhtar, M; Grachov, A; ... Tennyson, J; + view all Chubb, KL; Naumenko, O; Keely, S; Bartolotto, S; Macdonald, S; Mukhtar, M; Grachov, A; White, J; Coleman, E; Liu, A; Fazliev, AZ; Polovtseva, ER; Horneman, VM; Campargue, A; Furtenbacher, T; Császár, AG; Yurchenko, SN; Tennyson, J; - view fewer (2018) Marvel analysis of the measured high-resolution rovibrational spectra of H232S. Journal of Quantitative Spectroscopy and Radiative Transfer , 218 pp. 178-186. 10.1016/j.jqsrt.2018.07.012.

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Abstract

44325 measured and assigned transitions of H232S, the parent isotopologue of the hydrogen sulfide molecule, are collated from 33 publications into a single database and reviewed critically. Based on this information, rotation-vibration energy levels are determined for the ground electronic state using the Measured Active Rotational-Vibrational Energy Levels (MARVEL) technique. The ortho and para principal components of the measured spectroscopic network of H232S are considered separately. The verified set of 25 293 ortho- and 18 778 para- H232S transitions determine 3969 ortho and 3467 para energy levels. The MARVEL results are compared with alternative data compilations, including a theoretical variational linelist.

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