Daniels, LM;
Ling, S;
Savvin, SN;
Pitcher, MJ;
Dyer, MS;
Claridge, JB;
Slater, B;
... Rosseinsky, MJ; + view all
(2018)
A and B site doping of a phonon-glass perovskite oxide thermoelectric.
Journal of Materials Chemistry A
, 6
(32)
pp. 15640-15652.
10.1039/c8ta03739f.
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Abstract
By tuning the A site cation size it is possible to control the degree of octahedral distortion and ultimately structural symmetry in the new perovskite solid solution La0.5Na0.5-xKxTiO3, affording a rhombohedral-to-cubic transition as x increases above 0.4. The La3+and K+cations are distributed randomly across the A site leading to significant phonon disorder in cubic La0.5K0.5TiO3(Pm3m) which produces a phonon-glass with a thermal conductivity of 2.37(12) W m-1K-1at 300 K; a reduction of 75% when compared with isostructural SrTiO3. This simple cation substitution of Sr2+for La3+and K+maintains the flexible structural chemistry of the perovskite structure and two mechanisms of doping for the introduction of electronic charge carriers are explored; A site doping in La1-yKyTiO3or B site doping in La0.5K0.5Ti1-zNbzO3. The phonon-glass thermal conductivity of La0.5K0.5TiO3is retained upon doping through both of these mechanisms highlighting how the usually strongly coupled thermal and electronic transport can be minimised by mass disorder in perovskites. Precise control over octahedral distortion in A site doped La1-yKyTiO3, which has rhombohedral (R3c) symmetry affords lower band dispersions and increased carrier effective masses over those achieved in B site doped La0.5K0.5Ti1-zNbzO3which maintains the cubic (Pm3m) symmetry of the undoped La0.5K0.5TiO3parent. The higher Seebeck coefficients of A site doped La1-yKyTiO3yield larger power factors and lead to increased thermoelectric figures of merit and improved conversion efficiencies compared with the mechanism for B site doping.
| Type: | Article |
|---|---|
| Title: | A and B site doping of a phonon-glass perovskite oxide thermoelectric |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/c8ta03739f |
| Publisher version: | https://doi.org/10.1039/c8ta03739f |
| Language: | English |
| Additional information: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10055431 |
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