Matam, SK;
Howe, RF;
Thetford, A;
Catlow, CRA;
(2018)
Room temperature methoxylation in zeolite H-ZSM-5: an operando DRIFTS/mass spectrometric study.
Chemical Communications
, 54
(91)
pp. 12875-12878.
10.1039/c8cc07444e.
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Abstract
At high loading, methanol reacts under ambient conditions with acidic hydroxyls of H-ZSM-5 to methoxylate framework oxygen; while a significant proportion remains hydrogen bonded to the framework with a protonated geometry. The findings not only explain the data which have been published so far, but also pave a way forward for potential unravelling of the initial reaction steps in the relevant chemical processes.
| Type: | Article |
|---|---|
| Title: | Room temperature methoxylation in zeolite H-ZSM-5: an operando DRIFTS/mass spectrometric study |
| Location: | England |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/c8cc07444e |
| Publisher version: | https://doi.org/10.1039/c8cc07444e |
| Language: | English |
| Additional information: | This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10060924 |
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