Dicks, O; Cottom, J; Shluger, AL; Afanas'ev, V; (2019) The origin of negative charging in amorphous Al₂O₃ films: the role of native defects. Nanotechnology , 30 (20) 10.1088/1361-6528/ab0450.

Preview

Text Shluger_The origin of negative charging in amorphous Al₂O₃ films. The role of native defects_VoR.pdf - Published Version Download (1MB) | Preview

Abstract

Amorphous aluminum oxide Al₂O₃ (a-Al₂O₃) layers grown by various deposition techniques contain a significant density of negative charges. In spite of several experimental and theoretical studies, the origin of these charges still remains unclear. We report the results of extensive density functional theory calculations of native defects—O and Al vacancies and interstitials, as well as H interstitial centers—in different charge states in both crystalline α-Al₂O₃ and in a-Al₂O₃. The results demonstrate that both the charging process and the energy distribution of traps responsible for negative charging of a-Al₂O₃ films (Zahid et al 2010 IEEE Trans. Electron Devices 57 2907) can be understood assuming that the negatively charged O_{i} and V_{Al} defects are nearly compensated by the positively charged H_{i}, V_{O} and Al__{i} defects in as prepared samples. Following electron injection, the states of Al_{i}, V_{O} or H_{i} in the band gap become occupied by electrons and sample becomes negatively charged. The optical excitation energies from these states into the oxide conduction band agree with the results of exhaustive photo-depopulation spectroscopy measurements (Zahid et al 2010 IEEE Trans. Electron Devices 57 2907). This new understanding of the origin of negative charging of a-Al₂O₃ films is important for further development of nanoelectronic devices and solar cells.

Download activity - last month

Export as JSONCSVXML

Download activity - last 12 months

Export as CSVXMLJSON

Downloads by country - last 12 months

Export as JSONXMLCSV

Archive Staff Only

View Item