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Efficient Hybrid Solar Cells Based on Solution Processed Mesoporous TiO₂/Tin(II) Sulfide Heterojunctions

Ding, D; Rath, T; Lanzetta, L; Marin-Beloqui, JM; Haque, SA; (2018) Efficient Hybrid Solar Cells Based on Solution Processed Mesoporous TiO₂/Tin(II) Sulfide Heterojunctions. ACS Applied Energy Materials , 1 (7) pp. 3042-3047. 10.1021/acsaem.8b00590. Green open access

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Abstract

Tin monosulfide (SnS) is emerging as a promising absorber material for the development of low-cost, solution-processable solar cells. Herein, we present a straightforward, solution-based route for the preparation of tin monosulfide (SnS) films employing a green solvent, namely, tetrahydrofuran (THF). We show that the surface coverage and the morphology of the SnS films can be tuned by modification of the precursor solution composition and film deposition conditions. Furthermore, we explore the effect of a PEDOT:PSS interlayer and fabricate solar cells based on the following architecture: FTO/planar-TiO2/mesoporous-TiO2/SnS/P3HT/PEDOT:PSS/Ag. Devices based on this architecture are shown to exhibit power conversion efficiencies (PCEs) of 3.0%, thus demonstrating the potential of our method for the development of low-cost and environmentally friendly solar cells.

Type: Article
Title: Efficient Hybrid Solar Cells Based on Solution Processed Mesoporous TiO₂/Tin(II) Sulfide Heterojunctions
Open access status: An open access version is available from UCL Discovery
DOI: 10.1021/acsaem.8b00590
Publisher version: https://doi.org/10.1021/acsaem.8b00590
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: tin monosulfide (SnS) thin film solar cells hybrid solar cells solution processed deposition morphology mesoporous TiO2
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10091607
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