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Non-destructive collection survey of the historical Classense Library. Part I: Paper characterisation

Brown, N; Coppola, F; Modelli, A; Amicucci, F; Lichtblau, D; Strlič, M; (2020) Non-destructive collection survey of the historical Classense Library. Part I: Paper characterisation. Heritage Science , 8 (1) , Article 88. 10.1186/s40494-020-00432-w. Green open access

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Abstract

An innovative survey was conducted of the collections of the historical Biblioteca Classense, located in the urban area of Ravenna (Northern Italy). The survey aimed to evaluate the current conservation state of the book collections, where 297 paper-based items, including incunabula, manuscripts and books, dating from the 14th to the 20th century, were selected for analysis. This innovative survey was carried out non-destructively by assessing degradation visually and by measuring NIR spectral data followed by multivariate data analysis. Chemical and physical paper properties, important for paper characterisation and implementation of conservation strategies were determined, including paper type, pH, degree of polymerisation (DP), tensile strength, lignin, protein, and rosin content. This survey provided a significant quantitative dataset for rag paper covering a 600-year period. The analysis of DP changes over time allowed the first experimental estimation of the rate constant for historical rag paper, i.e., (4.2 ± 0.6)·10−7 year−1, which was validated with predictions based on the Collections Demography dose response function for historic paper taking into account the past climate in Ravenna. Statistical methods were employed to describe the correlations between the measured variables and different features of the books, suggesting that the degree of polymerisation can be used as a general proxy for rag paper mechanical strength.

Type: Article
Title: Non-destructive collection survey of the historical Classense Library. Part I: Paper characterisation
Open access status: An open access version is available from UCL Discovery
DOI: 10.1186/s40494-020-00432-w
Publisher version: http://dx.doi.org/10.1186/s40494-020-00432-w
Language: English
Additional information: Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/) applies to the data made available in this article, unless otherwise stated in a credit line to the data.
Keywords: NIR spectroscopy, Non-destructive survey, Classense Library, Historical book collections, Paper degradation, Rag paper
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of the Built Environment
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of the Built Environment > Bartlett School Env, Energy and Resources
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10110039
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