Galaverna, R;
Fernandes, LP;
Browne, DL;
Pastre, JC;
(2019)
Continuous flow processing as a tool for the generation of terpene-derived monomer libraries.
Reaction Chemistry & Engineering
, 4
(2)
pp. 362-367.
10.1039/c8re00237a.
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Abstract
We report the development of a continuous flow approach for the preparation of two bio-derived monomer libraries. A small range of terpenes (ocimene, myrcene, α-terpinene, α-phellandrene, isoprene, and farnesene) have been used as the base set for the library, with the first library derived from a Diels–Alder reaction with the platform chemical maleic anhydride. The second library requires the derivatization of the first through a hydrogenation reaction. The potential for scale-up of both libraries has been demonstrated, with the Diels–Alder process delivering 10.5 grams of the product in 3 hours and the hydrogenation process delivering 10 grams of the material in 16 hours.
| Type: | Article |
|---|---|
| Title: | Continuous flow processing as a tool for the generation of terpene-derived monomer libraries |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/c8re00237a |
| Publisher version: | https://doi.org/10.1039/C8RE00237A |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
| Keywords: | Science & Technology, Physical Sciences, Technology, Chemistry, Multidisciplinary, Engineering, Chemical, Chemistry, Engineering, GASEOUS AMMONIA, POLYMERIZATION, HYDROGENATION, COPOLYMERS, CHEMICALS, BIOMASS, GREEN |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy UCL > Provost and Vice Provost Offices > School of Life and Medical Sciences > Faculty of Life Sciences > UCL School of Pharmacy > Pharma and Bio Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10114328 |
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