Elsegood, Mark Robert James;
(1991)
Studies on ruthenium(II) and osmium(II) paracyclophane compounds.
Doctoral thesis (Ph.D), UCL (University College London).
Preview |
Text
out.pdf Download (8MB) | Preview |
Abstract
This thesis describes studies on ruthenium(II) and osmium(II) [22]paracyclophane compounds. Chapter 1 introduces the work, giving a historical background to the development of [22]paracyclophane chemistry. The properties of this compound and the syntheses of derived metal complexes are reviewed. Chapter 2 describes the synthesis of [Os(η6-C16H16)Cl2]2. Chapter 3 reports reactions of [Ru(η6-C16H16)C12]2 which lead to the formation of binuclear triply-bridged compounds of the type [(η6-C16H16)Ru(OMe)3Ru(η6-C16H16)][X] (Y=OMe-, OEt-, OH-, Cl-). Chapter 4 presents studies on the compounds [M(η6-arene)(η6-C16H16)][X]2. Chapter 5 presents the syntheses of organometallic chain compounds containing [22]paracyclophane. Chapter 6 draws together structural and spectroscopic data on the coordinated [22]paracyclophane ligand.
| Type: | Thesis (Doctoral) |
|---|---|
| Qualification: | Ph.D |
| Title: | Studies on ruthenium(II) and osmium(II) paracyclophane compounds |
| Open access status: | An open access version is available from UCL Discovery |
| Language: | English |
| Additional information: | Thesis digitised by ProQuest. |
| Keywords: | Pure sciences |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10114960 |
Archive Staff Only
 |
View Item |
