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Dissociative electron attachment cross sections for ro-vibrationally excited NO molecule and N⁻ anion formation

Laporta, V; Schneider, IF; Tennyson, J; (2020) Dissociative electron attachment cross sections for ro-vibrationally excited NO molecule and N⁻ anion formation. Plasma Sources Science and Technology , 29 (10) , Article 10LT01. 10.1088/1361-6595/abbae3. Green open access

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Abstract

Motivated by the huge need for data for non-equilibrium plasma modeling, a theoretical investigation of dissociative electron attachment to the NO molecule is performed. The calculations presented here are based on the local-complex-potential approach, taking into account five NO− resonances. Three specific channels of the process are studied, including the production of excited nitrogen atoms N(2D) and of its anions N−. Interpretation of the existing experimental data and their comparison with our theoretical result are given. A full set of ro-vibrationally-resolved cross sections and the corresponding rate coefficients are reported. In particular, a relatively large cross sections for N− ion formation at low energy of the incident electron and for vibrationally excited NO target are predicted. Finally, molecular rotation effects are discussed.

Type: Article
Title: Dissociative electron attachment cross sections for ro-vibrationally excited NO molecule and N⁻ anion formation
Open access status: An open access version is available from UCL Discovery
DOI: 10.1088/1361-6595/abbae3
Publisher version: https://doi.org/10.1088/1361-6595/abbae3
Language: English
Additional information: Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence (https://creativecommons.org/licenses/by/4.0/). Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10115856
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