Lee, R-C;
Franklin, J;
Tian, C;
Nordlund, D;
Doeff, M;
Kostecki, R;
(2021)
The origin of impedance rise in Ni-Rich positive electrodes for lithium-ion batteries.
Journal of Power Sources
, 498
, Article 229885. 10.1016/j.jpowsour.2021.229885.
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Abstract
The cycling performance of nickel-rich lithium nickel cobalt manganese oxide (NMC) electrodes in Li-ion batteries (LIBs) partially depends on the control of the kinetics of degradation processes that result in impedance rise. The impedance contribution from surface film formation at the NMC/electrolyte interfaces is highly dependent on the initial chemical composition and the structure of the NMC surfaces. Through comparison of film quantity and electrochemical performance of composite electrodes made of pristine- and surface treated-NMC materials, we are able to demonstrate that a simple surface treatment suppressed the subsequent film formation and reduced impedance rise of the Li/NMC half-cells during cycling. Detailed modelling of factors affecting cell impedance provide further insights to index individual interphase resistance, highlighting the underlying positive effects of the proposed surface treatment, and demonstrating the importance of homogeneous, electronically conducting matrices throughout the composite electrode.
| Type: | Article |
|---|---|
| Title: | The origin of impedance rise in Ni-Rich positive electrodes for lithium-ion batteries |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1016/j.jpowsour.2021.229885 |
| Publisher version: | https://doi.org/10.1016/j.jpowsour.2021.229885 |
| Language: | English |
| Additional information: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Chemical Engineering |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10127911 |
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