Ma, T-K;
Li, D;
Wilden, JD;
(2021)
Mechanistic studies of reactive oxygen species mediated electrochemical radical reactions of alkyl iodides.
Chemical Communications
10.1039/d1cc03019a.
(In press).
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Abstract
Mechanistic studies of a reactive oxygen species mediated electrochemical radical reaction of alkyl iodides are described. Hydroxyl radicals and ozone are identified to be the active species involved in the formation of alkyl radicals under mildly reducing potential (�1.0 V vs. Ag QRE) in buffered acidic conditions (pH 3.6).
| Type: | Article |
|---|---|
| Title: | Mechanistic studies of reactive oxygen species mediated electrochemical radical reactions of alkyl iodides |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/d1cc03019a |
| Publisher version: | https://doi.org/10.1039/d1cc03019a |
| Language: | English |
| Additional information: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. See: https://creativecommons.org/licenses/by/3.0/ |
| Keywords: | Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, SUPEROXIDE ANION, OZONE, REDUCTION, OXIDATION |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10133122 |
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