ShakeriHosseinabad, F; Daemi, SR; Momodu, D; Brett, DJL; Shearing, PR; Roberts, EPL; (2021) Influence of Flow Field Design on Zinc Deposition and Performance in a Zinc-Iodide Flow Battery. ACS Applied Materials & Interfaces , 13 (35) pp. 41563-41572. 10.1021/acsami.1c09770.

Preview	Text (Article) Randjbar Daemi_Revision submitted 22 July 20211.pdf - Accepted Version Download (18MB) | Preview
Preview	Text (Supporting Information) Randjbar Daemi_Revised supporting information_The influence of Flow Field Design on ZincDeposition and Performance in a Zinc-iodide FlowBattery.pdf - Accepted Version Download (7MB) | Preview

Abstract

Among the aqueous redox flow battery systems, redox chemistries using a zinc negative electrode have a relatively high energy density, but the potential of achieving high power density and long cycle life is hindered by dendrite growth at the anode. In this study, a new cell design with a narrow gap between electrode and membrane was applied in a zinc-iodide flow battery. In this design, some of the electrolyte flows over the electrode surface and a fraction of the flow passes through the porous felt electrode in the direction of current flow. The flow battery was tested under constant current density over 40 cycles, and the efficiency, discharge energy density, and power density of the battery were significantly improved compared to conventional flow field designs. The power density obtained in this study is one of the highest power densities reported for the zinc-iodide battery. The morphology of the zinc deposition was studied using scanning electron microscopy and optical profilometry. It was found that the flow through the electrode led to a thinner zinc deposit with lower roughness on the surface of the electrode, in comparison to the case where there was no flow through the electrode. In addition, inhibition of dendrite formation enabled operation at a higher range of current density. Ex situ tomographic measurements were used to image the zinc deposited on the surface and inside the porous felt. Volume rendering of graphite felt from X-ray computed tomography images showed that in the presence of flow through the electrode, more zinc deposition occurred inside the porous felt, resulting in a compact and thinner surface deposit, which may enable higher battery capacity and improved performance.

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