Al-Refaie, AF;
Changeat, Q;
Venot, O;
Waldmann, IP;
Tinetti, G;
(2022)
A Comparison of Chemical Models of Exoplanet Atmospheres Enabled by TauREx 3.1.
The Astrophysical Journal
, 932
(2)
, Article 123. 10.3847/1538-4357/ac6dcd.
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Abstract
Thermochemical equilibrium is one of the most commonly used assumptions in current exoplanet retrievals. As science operations with the James Webb Space Telescope (JWST) draw near and with the planned launch of Ariel, it is crucial to assess the underlying biases and assumptions made when applying self-consistent chemistry to spectral retrievals. Here we use the flexibility of TauREx 3.1 to cross-compare three state-of-the-art chemical equilibrium codes: ACE, FastChem, and GGchem. We simulate JWST spectra for ACE, FastChem, GGchem, and GGchem+condensation containing only the elements C, H, O, and N and spectra for FastChem, GGchem, and GGchem+condensation with a more extensive range of elements, giving seven simulated JWST spectra in total, and then cross-retrieve, giving a total of 56 retrievals. Our analysis demonstrates that, like-for-like, all chemical codes retrieve the correct parameters to within 1% of the truth. However, in retrievals, where the contained elements do not match the truth, parameters such as metallicity deviate by 20% while maintaining extremely low uncertainties <1%, giving false confidence. This point is of major importance for future analyses on JWST and Ariel, highlighting that self-consistent chemical schemes that do not employ the proper assumptions (missing species, fixed elemental ratios, condensation) are at risk of confidently biasing interpretations. Free chemistry retrievals employing parametric descriptions of the chemical profiles can provide alternative unbiased explorations.
| Type: | Article |
|---|---|
| Title: | A Comparison of Chemical Models of Exoplanet Atmospheres Enabled by TauREx 3.1 |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.3847/1538-4357/ac6dcd |
| Publisher version: | https://doi.org/10.3847/1538-4357/ac6dcd |
| Language: | English |
| Additional information: | This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third-party material in this article are included in the Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
| UCL classification: | UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy UCL > Provost and Vice Provost Offices > UCL BEAMS UCL |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10151374 |
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