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Facile One-Step Synthesis of PVDF Bead-on-String Fibers by Pressurized Gyration for Reusable Face Masks

Huang, Ruiran; Dai, Yanqi; Ahmed, Jubair; Edirisinghe, Mohan; (2022) Facile One-Step Synthesis of PVDF Bead-on-String Fibers by Pressurized Gyration for Reusable Face Masks. Polymers , 14 (21) p. 4498. 10.3390/polym14214498. Green open access

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Abstract

Single-use face masks pose a threat to the environment and are not cost-effective, which prompts the need for developing reusable masks. In this study, pressurized gyration (PG) successfully produced bead-on-string polyvinylidene fluoride (PVDF) fibers with fiber diameters ranging from 2.3 μm to 26.1 μm, and bead diameters ranging from 60.9 μm to 88.5 μm by changing the solution parameters. The effect of the solution parameters on the crystalline phase was studied by Fourier-transform infrared spectroscopy (FT-IR), where the β-phase contents of PG PVDF fibers reached over 75%. The fiber morphology and β-phase contents of PG PVDF fibers indicated the potential mechanical and electrostatic filtration efficiency of PG PVDF fibers, respectively. Additionally, the hydrophobicity was investigated by static water contact angle tests, and the PVDF fibers showed superior hydrophobicity properties (all samples above 125°) over commercial polypropylene (PP) single-use masks (approximately 107°). This study supports the notion that the PG PVDF fiber mats are a promising candidate for future reusable face masks.

Type: Article
Title: Facile One-Step Synthesis of PVDF Bead-on-String Fibers by Pressurized Gyration for Reusable Face Masks
Open access status: An open access version is available from UCL Discovery
DOI: 10.3390/polym14214498
Publisher version: https://doi.org/10.3390/polym14214498
Language: English
Additional information: This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third-party material in this article are included in the Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
Keywords: pressurized gyration; polyvinylidene fluoride (PVDF); bead-on-string fiber; fiber morphology; β-phase; hydrophobicity
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Engineering Science > Dept of Mechanical Engineering
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10159637
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