Germann, LS;
Carlino, E;
Taurino, A;
Magdysyuk, OV;
Voinovich, D;
Dinnebier, RE;
Bučar, DK;
(2023)
Modulating Thermal Properties of Polymers through Crystal Engineering.
Angewandte Chemie International Edition
, Article e202212688. 10.1002/anie.202212688.
(In press).
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Abstract
Crystal engineering has exclusively focused on the development of advanced materials based on small organic molecules. We now demonstrate how the cocrystallization of a polymer yields a material with significantly enhanced thermal stability but equivalent mechanical flexibility. Isomorphous replacement of one of the cocrystal components enables the formation of solid solutions with melting points that can be readily fine-tuned over a usefully wide temperature range. The results of this study credibly extend the scope of crystal engineering and cocrystallization from small molecules to polymers.
| Type: | Article |
|---|---|
| Title: | Modulating Thermal Properties of Polymers through Crystal Engineering |
| Location: | Germany |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/anie.202212688 |
| Publisher version: | https://doi.org/10.1002/anie.202212688 |
| Language: | English |
| Additional information: | © 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| Keywords: | Cocrystals, Crystal Engineering, Mechanochemistry, Polymers, Solid Solutions |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10165048 |
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