Zhao, Fei;
Li, Pinyi;
Liu, Xiaoyan;
Jia, Xiuwen;
Wang, Jiang;
Liu, Hong;
(2019)
Recent Advances in the Addition of Amide/Sulfonamide Bonds to Alkynes.
Molecules
, 24
(1)
, Article 164. 10.3390/molecules24010164.
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Abstract
The addition of amide/sulfonamide bonds to alkynes is not only one of the most important strategies for the direct functionalization of carbon–carbon triple bonds, but also a powerful tool for the downstream transformations of amides/sulfonamides. The present review provides a comprehensive summary of amide/sulfonamide bond addition to alkynes, including direct and metal-free aminoacylation, based-promoted aminoacylation, transition-metal-catalyzed aminoacylation, organocatalytic aminoacylation and transition-metal-catalyzed aminosulfonylation of alkynes up to December 2018. The reaction conditions, regio- and stereoselectivities, and mechanisms are discussed and summarized in detail.
| Type: | Article |
|---|---|
| Title: | Recent Advances in the Addition of Amide/Sulfonamide Bonds to Alkynes |
| Location: | Switzerland |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.3390/molecules24010164 |
| Publisher version: | https://doi.org/10.3390/molecules24010164 |
| Language: | English |
| Additional information: | © The Author(s). This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/ |
| Keywords: | amide bond; sulfonamide bond; alkynes; addition reaction; aminoacylation; aminosulfonylation |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10167636 |
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