Malde, Roshni;
Richards, Daniel A;
Salerno, Luigia;
Zhao, Yanbo;
Karu, Kersti;
Chudasama, Vijay;
Baker, James R;
(2023)
A Light‐Induced Decarboxylative‐Elimination of Substituted Maleimides as a Strategy Towards Triggered Photorelease.
European Journal of Organic Chemistry
, Article e202201372. 10.1002/ejoc.202201372.
(In press).
Preview |
Text
A Light Induced Decarboxylative Elimination of Substituted Maleimides.pdf - Published Version Download (2MB) | Preview |
Abstract
Herein we report on photodecarboxylations of various substituted maleimides, resulting in an elimination reaction. Furthermore, we establish facile wavelength tunability through modulation of the maleimide double bond substituents. We envisage that these versatile reagents, which are readily constructed and diversified by nucleophilic substitution reactions on bromomaleimides, will offer new opportunities for triggered photorelease.
| Type: | Article |
|---|---|
| Title: | A Light‐Induced Decarboxylative‐Elimination of Substituted Maleimides as a Strategy Towards Triggered Photorelease |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1002/ejoc.202201372 |
| Publisher version: | https://doi.org/10.1002/ejoc.202201372 |
| Language: | English |
| Additional information: | 2023 The Authors. European Journal of Organic Chemistry published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| Keywords: | photodecarboxylation, photocleavable linker, photo trigger, maleimide, thiomaleimide |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10169250 |
Archive Staff Only
 |
View Item |
