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Economic Benefits of Waste Pickling Solution Valorization

Gueccia, Rosa; Bogle, David; Randazzo, Serena; Tamburini, Alessandro; Cipollina, Andrea; Winter, Daniel; Koschikowski, Joachim; (2022) Economic Benefits of Waste Pickling Solution Valorization. Membranes , 12 (2) , Article 114. 10.3390/membranes12020114. Green open access

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Abstract

An integrated hybrid membrane process, composed of a diffusion dialysis (DD), a membrane distillation (MD) and a reactive precipitation unit (CSTR), is proposed as a promising solution for the valorization and onsite recycling of pickling waste streams. An economic analysis was performed aiming to demonstrate the feasibility of the developed process with a NPV of about EUR 40,000 and a DPBP of 4 years. The investment and operating costs, as well as the avoided costs and the benefits for the company operating the plant, were analyzed with an extensive cost tracking exercise and through face-to-face contact with manufacturers and sector leaders. A mathematical model was implemented using the gPROMS modelling platform. It is able to simulate steady state operations and run optimization analysis of the process performance. The impact of key operating and design parameters, such as the set-point bath concentration and the DD and MD membrane areas, respectively, was investigated and the optimal arrangement was identified. Finally, operating variables and design parameters were optimized simultaneously in a nonlinear framework as a tradeoff between profitability and environmental impact. We show how the integration of new technologies into the traditional pickling industry could provide a significant benefit for the issues of process sustainability, which are currently pressing.

Type: Article
Title: Economic Benefits of Waste Pickling Solution Valorization
Location: Switzerland
Open access status: An open access version is available from UCL Discovery
DOI: 10.3390/membranes12020114
Publisher version: https://doi.org/10.3390/membranes12020114
Language: English
Additional information: © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Keywords: industrial wastewater; pickling; economic analysis; optimization; diffusion dialysis; membrane distillation
UCL classification: UCL
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10172172
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