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Electron scattering on molecular nitrogen: common gas, uncommon cross sections

Song, MY; Cho, H; Karwasz, GP; Kokoouline, V; Tennyson, J; (2023) Electron scattering on molecular nitrogen: common gas, uncommon cross sections. European Physical Journal D , 77 (6) , Article 105. 10.1140/epjd/s10053-023-00687-5. Green open access

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Abstract

We discuss peculiar features of electron scattering on the N2 molecule and the N2+ ion, that are important for modeling plasmas, Earth’s and other planets’ atmospheres. These features are, among others: the resonant enhancement of the vibrational excitation in the region of the shape resonance around 2.4 eV, the resonant character of some of electronic excitation channels (and high values of these cross sections, both for triplet and singlet states), high cross section for the dissociation into neutrals, high cross sections for elastic scattering (and electronic transitions) on metastable states. For the N2+ ion we discuss both dissociation and the dissociative ionization, leading to the formation of atoms in excited states, and dissociative recombination which depends strongly on the initial vibrational state of the ion. We conclude that the theory became an indispensable completion of experiments, predicting many of partial cross sections and their physical features. We hope that the data presented will serve to improve models of nitrogen plasmas and atmospheres. Graphical abstract: [Figure not available: see fulltext.].

Type: Article
Title: Electron scattering on molecular nitrogen: common gas, uncommon cross sections
Open access status: An open access version is available from UCL Discovery
DOI: 10.1140/epjd/s10053-023-00687-5
Publisher version: https://doi.org/10.1140/epjd/s10053-023-00687-5
Language: English
Additional information: Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10173160
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