Nason, Charlie AF;
Xu, Yang;
(2023)
Pre-intercalation: A valuable approach for the improvement of post-lithium battery materials.
eScience
, Article 100183. 10.1016/j.esci.2023.100183.
(In press).
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Abstract
With the growing concern around the sustainability and supply of lithium, the need for alternative rechargeable energy storage technologies has become ever more pressing. Sodium-, potassium-, magnesium-, and zinc-ion batteries are fast becoming viable alternatives but are held back by capacity, rate and stability problems that have not developed comparably to lithium-ion batteries. To overcome these shortcomings and reduce the reliance on lithium, electrode materials used for these post-lithium batteries must be improved. Pre-intercalation of foreign species into the lattice of promising electrode materials can enhance their electrochemical performance in comparison to the un-pre-intercalated counterparts, closing the performance gap with lithium-ion batteries. This review article covers the common methods of pre-intercalating foreign species into electrode materials, the resulting structural effects and the improvements that are observed in the materials’ electrochemical performance for post-lithium batteries. Timely and impactful work reported previously are summarised as examples of these improvements, demonstrating the value and ever-growing importance of pre-intercalation in today’s battery landscape.
Type: | Article |
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Title: | Pre-intercalation: A valuable approach for the improvement of post-lithium battery materials |
Open access status: | An open access version is available from UCL Discovery |
DOI: | 10.1016/j.esci.2023.100183 |
Publisher version: | https://doi.org/10.1016/j.esci.2023.100183 |
Language: | English |
Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions. |
Keywords: | Intercalation; Post-Lithium; Batteries; Energy Storage; Electrode Materials; Ion Diffusion; Active Sites |
UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10177194 |
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