Wang, Zhaoyang;
Du, Zijuan;
Liu, Yiyang;
Knapp, Caroline E;
Dai, Yuhang;
Li, Jianwei;
Zhang, Wei;
... He, Guanjie; + view all
(2023)
Metal–organic frameworks and their derivatives for optimizing lithium metal anodes.
eScience
, Article 100189. 10.1016/j.esci.2023.100189.
(In press).
Preview |
Text
He_Metal organic frameworks and their derivatives for optimizing lithium metal anodes_Pre-proof.pdf - Accepted Version Download (27MB) | Preview |
Abstract
Lithium metal anodes (LMAs) have been considered the ultimate anode materials for next-generation batteries. However, the uncontrollable lithium dendrite growth and huge volume expansion that can occur during charge and discharge seriously hinder the practical application of LMAs. Metal–organic framework (MOF) materials, which possess the merits of huge specific surface area, excellent porosity, and flexible composition/structure tunability, have demonstrated great potential for resolving both of these issues. This article first explores the mechanism of lithium dendrite formation as described by four influential models. Subsequently, based on an in-depth understanding of these models, we propose potential strategies for utilizing MOFs and their derivatives to suppress lithium dendrite growth. We then provide a comprehensive review of research progress with respect to various applications of MOFs and their derivatives to suppress lithium dendrites and inhibit volume expansion. The paper closes with a discussion of perspectives on future modifications of MOFs and their derivatives to achieve stable, dendrite-free lithium metal batteries.
| Type: | Article |
|---|---|
| Title: | Metal–organic frameworks and their derivatives for optimizing lithium metal anodes |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1016/j.esci.2023.100189 |
| Publisher version: | https://doi.org/10.1016/j.esci.2023.100189 |
| Language: | English |
| Additional information: | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) License. |
| Keywords: | Metal–organic frameworks; Lithium metal batteries; Lithium metal anodes, Lithium dendrite formation mechanism; Lithium dendrite inhibition strategy |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10178636 |
Archive Staff Only
 |
View Item |
