Mertzenich, CL;
Papaefstathiou, GS;
Friščić, T;
Hamilton, TD;
Bučar, DK;
Swenson, DC;
MacGillivray, LR;
(2021)
Inverted metal–organic frameworks: isoreticular decoration with organic anions using principles of supramolecular chemistry.
Journal of Coordination Chemistry
, 74
(1-3)
pp. 169-177.
10.1080/00958972.2021.1880004.
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Abstract
A structural study of two-dimensional inverted metal–organic frameworks demonstrates that the interior cavities of the framework structures can be systematically modified by changing the organic anion of a Cu(II)-paddlewheel unit. Changing the anion allows modifications to the shapes and sizes of the cavities in a series of isoreticular frameworks. The construction of the frameworks is based on the application of a tetrafunctional organic cyclobutane ligand synthesized in the organic solid state.
| Type: | Article |
|---|---|
| Title: | Inverted metal–organic frameworks: isoreticular decoration with organic anions using principles of supramolecular chemistry |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1080/00958972.2021.1880004 |
| Publisher version: | http://dx.doi.org/10.1080/00958972.2021.1880004 |
| Language: | English |
| Additional information: | This version is the author accepted manuscript. For information on re-use, please refer to the publisher's terms and conditions. |
| Keywords: | MOF, coordination polymer, crystal engineering |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/10186074 |
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