Groeneman, RH; Bučar, DK; MacGillivray, LR; Atwood, JL; (2021) Quasi self-inclusion of a 1-D coordination polymer within a 2-D hydrogen-bonded grid: a chaperone effect. Journal of Coordination Chemistry , 74 (1-3) pp. 162-168. 10.1080/00958972.2021.1879383.

Preview

Text Bucar_Quasi self-inclusion of a 1-D coordination polymer within a 2-D hydrogen-bonded grid_AAM.pdf Download (254kB) | Preview

Abstract

The one-dimensional (1-D) coordination polymer [Ni(bdc)(pico)2(H2O)2] (where bdc = terephthalate, pico = 4-picoline) is hosted within a two-dimensional (2-D) hydrogen-bonded grid [Ni(bdc)(pico)2(H2O)2]·(pyz) (where pyz = pyrazine). Both coordination polymers are comprised of the same components and differ only by their hydrogen-bonding patterns. The polymers of the 2-D grids engage in O–H···N hydrogen bonds to the included pyz. The grid contains rhombohedral cavities that lie along the crystallographic ac-plane. The grids self-assemble by C–H···π interactions involving the methyl group of pico and the aromatic ring of the bdc anion. The included polymer interacts with the 2-D grids via O–H···O hydrogen bonds involving coordinated water and the bdc anion.

Download activity - last month

Export as JSONCSVXML

Download activity - last 12 months

Export as XMLCSVJSON

Downloads by country - last 12 months

Export as XMLCSVJSON

Archive Staff Only

View Item