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Chemical Resolution at Ionic Crystal Surfaces Using Dynamic Atomic Force Microscopy with Metallic Tips

Teobaldi, G; Lammle, K; Trevethan, T; Watkins, M; Schwarz, A; Wiesendanger, R; Shluger, AL; (2011) Chemical Resolution at Ionic Crystal Surfaces Using Dynamic Atomic Force Microscopy with Metallic Tips. PHYS REV LETT , 106 (21) , Article 216102. 10.1103/PhysRevLett.106.216102. Green open access

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Abstract

We demonstrate that well prepared and characterized Cr tips can provide atomic resolution on the bulk NaCl(001) surface with dynamic atomic force microscopy in the noncontact regime at relatively large tip-sample separations. At these conditions, the surface chemical structure can be resolved yet tip-surface instabilities are absent. Our calculations demonstrate that chemical identification is unambiguous, because the interaction is always largest above the anions. This conclusion is generally valid for other polar surfaces, and can thus provide a new practical route for straightforward interpretation of atomically resolved images.

Type: Article
Title: Chemical Resolution at Ionic Crystal Surfaces Using Dynamic Atomic Force Microscopy with Metallic Tips
Open access status: An open access version is available from UCL Discovery
DOI: 10.1103/PhysRevLett.106.216102
Publisher version: http://dx.doi.org/10.1103/PhysRevLett.106.216102
Language: English
Additional information: © 2011 American Physical Society
Keywords: WORK FUNCTION
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery-pp.ucl.ac.uk/id/eprint/1314302
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