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Dissociative recombination and vibrational excitation of BF⁺ in low energy electron collisions

Zs Mezei, J; Colboc, F; Pop, N; Ilie, S; Chakrabarti, K; Niyonzima, S; Lepers, M; ... Schneider, IF; + view all (2016) Dissociative recombination and vibrational excitation of BF⁺ in low energy electron collisions. Plasma Sources Science and Technology , 25 (5) , Article 055022. 10.1088/0963-0252/25/5/055022. Green open access

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Abstract

The latest molecular data—potential energy curves and Rydberg-valence interactions—characterising the super-excited electronic states of BF are reviewed in order to provide the input for the study of their fragmentation dynamics. Starting from this input, the main paths and mechanisms of BF+ dissociative recombination and vibrational excitation are analysed. Their cross sections are computed for the first time using a method based on the multichannel quantum defect theory (MQDT), and Maxwellian rate-coefficients are calculated and displayed in ready-to-be-used format for low temperature plasma kinetics simulations.

Type: Article
Title: Dissociative recombination and vibrational excitation of BF⁺ in low energy electron collisions
Open access status: An open access version is available from UCL Discovery
DOI: 10.1088/0963-0252/25/5/055022
Publisher version: http://doi.org/10.1088/0963-0252/25/5/055022
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: non-equilibrium plasma, plasma immersion ion implantation, molecular cations, dissociative recombination, electron impact vibrational excitation, excited states, multichannel quantum defect theory
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery-pp.ucl.ac.uk/id/eprint/1527353
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