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High-resolution absorption measurements of NH₃ at high temperatures: 2100–5500 cm⁻¹

Barton, EJ; Yurchenko, SN; Tennyson, J; Clausen, S; Fateev, A; (2017) High-resolution absorption measurements of NH₃ at high temperatures: 2100–5500 cm⁻¹. Journal of Quantitative Spectroscopy and Radiative Transfer , 189 pp. 60-65. 10.1016/j.jqsrt.2016.11.009. Green open access

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Abstract

High-resolution absorption spectra of NH3 in the region 2100–5500 cm⁻¹ at 1027 °C and approximately atmospheric pressure (1045±3 mbar) are measured. An NH₃ concentration of 10% in volume fraction is used in the measurements. Spectra are recorded in a high-temperature gas-flow cell using a Fourier Transform Infrared (FTIR) spectrometer at a nominal resolution of 0.09 cm⁻¹. The spectra are analysed by comparison to a variational line list, BYTe, and experimental energy levels determined using the MARVEL procedure. 2308 lines have been assigned to 45 different bands, of which 1755 and 15 have been assigned or observed for the first time in this work.

Type: Article
Title: High-resolution absorption measurements of NH₃ at high temperatures: 2100–5500 cm⁻¹
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.jqsrt.2016.11.009
Publisher version: http://dx.doi.org/10.1016/j.jqsrt.2016.11.009
Language: English
Additional information: This version is the author accepted manuscript. For information on re-use, please refer to the publisher’s terms and conditions.
Keywords: High temperature, Ammonia, Absorption, FTIR spectroscopy, High-temperature flow gas cellBYTe, Line assignments
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy
URI: https://discovery-pp.ucl.ac.uk/id/eprint/1533048
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