Le, M.D.;
Walker, H.C.;
McEwen, K.A.;
Gouder, T.;
Huber, F.;
Wastin, F.;
(2008)
Photoelectron spectroscopy of NpPd3 and PuPd3.
Journal of Physics Condensed Matter
, 20
(27)
p. 275220.
10.1088/0953-8984/20/27/275220.
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Abstract
We present the results of x-ray and ultraviolet photoelectron spectroscopy of NpPd3 and PuPd3. The spectra indicate that for both compounds, the 5f electrons are well localized on the actinide sites. Comparison with bulk measurements indicates that for NpPd3 the electrons have a valence of Np3+ and thus a ground state 5f4 with a Hund's rules 5I4 configuration. Similarly for PuPd3, we find a Pu3+ valence, 5f5 ground state and a Hund's rules 6H5/2 configuration.
| Type: | Article |
|---|---|
| Title: | Photoelectron spectroscopy of NpPd3 and PuPd3 |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1088/0953-8984/20/27/275220 |
| Publisher version: | http://dx.doi.org/10.1088/0953-8984/20/27/275220 |
| Language: | English |
| UCL classification: | UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > London Centre for Nanotechnology UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Physics and Astronomy |
| URI: | https://discovery-pp.ucl.ac.uk/id/eprint/8244 |
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