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A readily accessible porous organic polymer facilitates high-yielding Knoevenagel condensation at room temperature both in water and under solvent-free mechanochemical conditions

Sarma, P; Sarmah, KK; Kakoti, D; Mahanta, SP; Adassooriya, NM; Nandi, G; Das, PJ; ... Thakuria, R; + view all (2021) A readily accessible porous organic polymer facilitates high-yielding Knoevenagel condensation at room temperature both in water and under solvent-free mechanochemical conditions. Catalysis Communications , 154 , Article 106304. 10.1016/j.catcom.2021.106304. Green open access

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Abstract

A novel nitrogen-rich amorphous porous organic polymer has been synthesized using a microwave-assisted process. Its high chemical stability, reusability and poor solubility enable the use of the porous polymer as a metal-free heterogeneous catalyst for C–C bond formation at ambient temperature under environmentally benign conditions.

Type: Article
Title: A readily accessible porous organic polymer facilitates high-yielding Knoevenagel condensation at room temperature both in water and under solvent-free mechanochemical conditions
Open access status: An open access version is available from UCL Discovery
DOI: 10.1016/j.catcom.2021.106304
Publisher version: https://doi.org/10.1016/j.catcom.2021.106304
Language: English
Additional information: © 2021 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Keywords: Porous organic polymers, Catalysis, Amorphous materials, Mechanochemistry, Knoevenagel condensation
UCL classification: UCL
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: https://discovery-pp.ucl.ac.uk/id/eprint/10135375
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